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Subject: Photo Mask Corrosion

Figure 1
An assessment of the protective
ability of Intercept Technology and VCI on photo masks has been
performed.
One sample of a photo mask was cleaned
with an isopropanol dip, dried in flowing nitrogen and cut into
two pieces each being approximately 6" X 8". One piece was placed
in a standard 0.008" thick one sided static intercept bag. The second
was placed in an over-wrap of 0.006" thick X 14.5" X 11.5"VCI impregnated
paper as supplied by the photo-mask manufacturer. This Kraft wrapped
mask was placed in a .003" LDPE plastic bag and heat-sealed.
The test chamber was an 8-liter
bell jar, which was placed on a Thermolyne magnetic stirrer hot
plate. A one-inch Teflon coated stirring bar along with 25 ml of
dionized water was placed in the bottom of the vessel. The two bags
were placed in the bell jar suspended 3" above the bottom on an
open ceramic shelf.
The stirred was set at a medium
rate and the temperature set at 110 degrees F.
The test duration was 45 Days.
The results are seen in figure 1.
The high permeation rate of the
LDPE bag and long-term exposure to condensed water cause a catastrophic
failure of the VCI scheme.
There was a fingerprint on the
edge of the screen protected in Intercept - a site of contamination.
The Intercept bag had a pinhole in the bottom seam that allowed
water to accumulate inside the bag right in the proximity of the
fingerprint. The active neutralization function of the Intercept
Technology limited corrosion products to the immediate area surrounding
the pinhole. This points up the need to ensure that all product
going into Intercept bags be clean and non-contaminated.
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